Recovery of polyphenols from camu-camu (Myrciaria dubia H.B.K. McVaugh) depulping residue by cloud point extraction

In this study the potential of cloud point extraction formed by a non-ionic surfactant was used in order to separate polyphenols from industrial residues of camu-camu. The effects of operational conditions of the cloud point extraction (CPE) on the polyphenol recovery and volumetric ratio were investigated. The results showed a maximum recovery of 95.71% that was obtained using 7.0 wt% Triton X-114, native pH (3.25), and 80 wt% polyphenol extract at 30 °C. The use of cloud point extraction was successful to recover the polyphenols from agroindustrial residue since it is a simple as well as of low-cost technique.     

Applications of Diglycolamide Based Solvent Extraction Processes in Spent Nuclear Fuel Reprocessing,Part 1: TODGA

Over the last decade there has been much interest in the applications of diglycolamide (DGA) ligands for the extraction of the trivalent lanthanide and actinide ions from PUREX high active raffinates or dissolved spent nuclear fuel. Of the DGAs, the N,N,N’,N’-tetraoctyldiglycolamide (TODGA) is the best known and most widely studied. A number of new actinide separation processes have been proposed based on extraction with TODGA. This review covers TODGA-based processes and extraction data, specifically focusing on how phase modifiers have been used to increase metal loading and thus enhance the operating process envelopes. Effects of third phase formation and the organic phase speciation are reviewed in this context. Relevant aspects of the extraction chemistry of important solvents (TODGA-modifier-diluent combinations) are described and their performances demonstrated by a consideration of the published flowsheet tests. It is seen that modifiers are successfully enabling the use of TODGA in actinide separation processes but to date the identification and testing of suitable modifiers has been rather empirical. There is a growing understanding of the fundamental chemistry occurring in the organic phase and how that affects extractant speciation and metal loading capacity but studies are still needed if TODGA-based flowsheets are to become an industrially deployable option for minor actinide (MA) recovery processes.     

基于增强算子的污染土雷达图像特征提取仿真

针对雷达图像特征提取效率低、精度不高等问题,提出一种基于增强算子的污染土雷达图像特征提取方法。首先使用多尺度非均匀滤波把含有噪声与不含噪声的像素点灰度值、构成因素及像素加权灰度密度三个特征进行划分,完成雷达图像去噪。其次提出增强算子方法,将图像数据转变至图像的空间域,以此判断污染土雷达图像内是否存在对比度不高区域和细微区域。最后采用灰色关联分析计算超像素之间的相似度,运用MLS增强算子对曲面进行拟合,通过高斯曲率与平均曲率构建出特征判断准则,提高图像特征提取完整性,实现污染土雷达图像特征的精准提取。仿真结果表明,与传统方法相比所提方法计算速度较快,雷达特征提取效率较高,可大幅提升污染土雷达图像特征提取准确率。     

Enriching Context Information for Entity Linking with Web Data

Journal of Computer Science and Technology - Entity linking (EL) is the task of determining the identity of textual entity mentions given a predefined knowledge base (KB). Plenty of existing...     

严重突出煤层穿层钻孔“钻冲筛运”一体化瓦斯治理技术研究与应用

鹤煤公司八矿地质构造复杂、断层褶曲发育,尤其井田深部断层多,并且煤层透气性低且松软,打钻塌孔、喷孔严重,瓦斯抽放效果不好,给煤炭开采和瓦斯综合治理带来了困难。针对鹤煤公司八矿穿层钻孔瓦斯治理技术措施进行井下现场探索与研究,通过在3205底抽巷经过多次技术方案论证、实践,摸索出一套钻冲筛运一体化整套技术流程,并分析高压水力冲孔瓦斯涌出特征、有效影响半径。通过采用高压水力冲孔、振动筛选、转载装运,提高了水力冲孔效果和效率,改善了工作环境。     

陶瓷超滤膜用于盐湖卤水提锂合格液的中试研究

为解决纳滤膜用于盐湖卤水镁锂分离中长时间运行后出现通量下降、膜污染和分离效率下降的问题,开展了将陶瓷超滤膜作为纳滤预处理措施用于盐湖卤水提锂合格液的中试研究。中试设在吸附提锂车间,进水为提锂工序中的合格液。结果表明,在冬天低温环境合格液浊度<50 NTU的条件下,以及在合格液浊度上升至50~170 NTU的极端进水水质条件下,陶瓷超滤膜均可在300 L/（m ²·h）的测试通量下稳定运行,过滤时间为30~50 min/周期。产水浊度稳定<0.1 NTU,优于后续纳滤系统进水要求。     

采用顶板梳状定向钻孔瓦斯抽采技术研究

通过对顶板梳状定向钻孔瓦斯抽采技术关键原理进行理论研究,结合大阳煤矿回采工作面应用顶板梳状定向钻孔瓦斯抽采的实际情况,阐述了大阳煤矿应用梳状定向钻孔产生的效果及经济效益.通过研究,推广顶板梳状定向钻孔瓦斯抽采技术,有助于实现回采工作面在采煤的同时安全高效的抽采瓦斯.     

白云鄂博矿焙烧浸出-萃取沉淀分离稀土及钍的试验研究

采用焙烧浸出-萃取沉淀法从白云鄂博稀土精矿中分离稀土和钍,得到最佳焙烧浸出条件为: 矿酸比1∶1.5、焙烧时间1 h、焙烧温度200 ℃、水浸液固比8∶1、水浸时间4 h、水浸温度50 ℃,最佳条件下CeO₂、La₂O₃、Nd₂O₃、Pr₆O₁₁、Sm₂O₃和ThO₂浸出率分别为80.77%、69.24%、95.71%、76.82%、93.31% 和98.13%。采用羧酸类萃取-沉淀剂从浸液中萃取分离稀土和钍,在萃取-沉淀剂皂化度70%、料液pH=3.1、萃取-沉淀剂和钍的摩尔比4∶1的最佳条件下,稀土和钍萃取-沉淀率分别为19%和90%,实现了稀土和钍的有效分离。     

Concept for a Hydrometallurgical Processing of a Copper-Cobalt-Nickel Alloy Made from Manganese Nodules

The processing of manganese nodules for the production of raw materials has been a subject of research for many decades. The nodules contain many valuable metals like copper, cobalt and nickel. In recent years, the German Federal Institute for Geoscience and Natural Resources developed a process for the processing of manganese nodules based on a combined pyro- and a hydrometallurgical route. Clausthal University of Technology was assigned to develop the hydrometallurgical process for the treatment of a FeNiCuCo alloy. The developed process consists of pressurized sulfuric acid leaching with the suppression of hydrogen gas formation, precipitation and solvent extraction.     

液相色谱-串联质谱法测定进出口人参、西洋参中蚜灭磷等6种农药

建立了人参、西洋参中凝胶色谱-固相萃取-液相色谱-串联质谱法测定蚜灭磷、吡虫啉、涕灭威、甲基内吸磷、甲硫威、辛硫磷6种农药的分析方法。样品经丙酮超声提取,凝胶色谱(GPC)净化后,固相萃取(SPE)净化,在HPLC/MS/MS多反应监测(MRM)模式下进行了定性和定量分析方法。在上述检测方法条件下,所测的6种农药的最低检出限为0.01 mg/kg,回收率范围为79.2%~107.3%,线性范围为0.01~0.2 mg/kg。